White Paper / Technical Paper Foundational research by Fluid Tech CTO Mark Denton · WM 2011

Development and Testing of Two Vitrification-Compatible Classes of Ion-Specific Media

A foundational paper on the Ion-Specific Media (ISM) approach that Fluid Tech's WTZ and FHA media build on — two novel inorganic, vitrification-compatible media classes engineered to capture the recalcitrant isotopes (Cs-137, Sr-90, Tc-99, I-129) that drive supplemental treatment at the Hanford Waste Treatment Plant.

Authors Mark S. Denton; William D. Bostick (MCLinc) Venue WM2011 · Paper 11001

Technical conference paper

Foundational research by our Chief Technology Officer. This paper was authored by Mark S. Denton — now Fluid Tech's CTO — during his tenure at Kurion, Inc., and presented at WM2011. It is included here because it documents the ion-specific media science that Fluid Tech's WTZ® and FHA media are built on; the summary below is for reference, and full details are in the cited paper.

01 Overview

The paper develops and tests two novel classes of Ion-Specific Media (ISM) — exclusively inorganic media designed to be compatible with downstream stabilization (solidification and vitrification) and to act as the final stabilized waste form. The purpose of such high-capacity, high-specificity ISM is to remove the recalcitrant isotopes — Cs-137, Sr-90, Tc-99 and I-129 — during supplemental treatment (pretreatment, off-spec tanks and secondary waste), and place them into very small packages for on-site storage or high-level-waste vitrification. Because the media are inorganic, leach-resistant, non-hydrogen-generating, and sluiceable, they are well suited to long-term in-tank or dry storage.

02 Why it matters

  • Targets the isotopes that drive classification: capturing Cs, Sr, Tc and I lets a waste-treatment plant minimize the volume of high-level waste requiring vitrification and maximize the lower-activity feed.
  • The medium becomes the waste form: vitrification-compatible, inorganic media can be immobilized directly — leach-resistant, non-hydrogen-generating, and sluiceable.
  • The lineage behind the product line: this ISM science underpins Fluid Tech's current WTZ® (zeolite) and FHA (hydroxyapatite) media.

03 How it was tested

A full spectrum of ISM was down-selected and evaluated on batch reactors and columns at analytical and bench scale, against:

  • Near-neutral pH surrogates and actual feeds;
  • Waste Treatment Plant secondary-waste-stream surrogates (pH ~8–9);
  • Strontium (Sr-90) removal from chelated tanks (e.g., AN-102 and AN-107, pH 12–13);
  • High-alkali WTP cesium pretreatment (pH ~14).

Testing was also carried out on actual commercial nuclear-power-plant waste streams — at the authors' Oak Ridge laboratory and independently on site at the Seabrook Nuclear Power Station by the Electric Power Research Institute (EPRI), including fuel-pool and Boron Waste Storage Tank waters.

04 Citation

Denton, M. S. (Kurion, Inc.); Bostick, W. D. (Materials and Chemistry Laboratory, Inc.). Development and Testing of Two Novel and Vitrification-Compatible Classes of Ion-Specific Media for Application on the Hanford Waste Treatment Plant Supplemental Pretreatment and Secondary Waste Streams (Paper 11001). WM2011 Conference, Phoenix, AZ.

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